The Public Sector Mapping Agreement (PSMA) allows free access to many more mapping layers than the free (to everyone) OpenData... but only to eligible public sector bodies.

For full details look at the Ordnance Survey website.

Members may order free maps for download, delivery on DVD or even hard drive.

Layers provided include: Detailed address products

You must sign-up with Ordnance Survey BEFORE you can access the PSMA area of their website